Luận án Nghiên cứu quá trình hydrodeclo hóa một số hợp chất pcbs trong pha lỏng sử dụng hydro nội sinh trên xúc tác Pd/OMC và Pd-Cu/OMC

42 với hiệu quả cao. 3. Xác định được mô hình động học phản ứng giả bậc một và một số đặc điểm động học gồm năng lượng hoạt hóa, hằng số tốc độ phản ứng của quá trình hydrodeclo hóa PCB-28 sử dụng các xúc tác nêu trên. Bước đầu kết hợp giữa tính 133 toán lý thuyết bằng phần mềm Gaussian 09 với thực nghiệm đề đề xuất xu hướng tách loại clo và cơ chế phản ứng HDC PCB-28. * Hướng nghiên cứu tiếp theo: 1. Nghiên cứu, thử nghiệm xử lý các đối tượng ô nhiễm PCB ở Việt Nam như dầu biến thế, đất, trầm tích ô nhiễm PCB 2. Nghiên cứu làm rõ các sản phẩm trung gian trong quá trình declo hóa PCB- 28 cũng như các PCB khác. Trên cơ sở đó để xây dựng cơ chế declo hóa các PCB một cách tường minh hơn. 3. Nghiên cứu, thử nghiệm hoàn nguyên xúc tác, và tăng độ bền xúc tác để từng bước sử dụng trong thực tế. 134 DANH MỤC CÁC CÔNG TRÌNH KHOA HỌC ĐÃ CÔNG BỐ CT1. Nguyễn Quang Thắng, Trần Thị Hải Yến, Tô Văn Thiệp, Nguyễn Trọng Nghĩa*, Nguyễn Hồng Liên, Vũ Hùng Sinh, (2019), "Nghiên cứu lý thuyết phản ứng hydrodeclo hóa PCB-28", Tạp chí Hóa học, T.6, N1, tr.73-78. CT2. Nguyễn Quang Thắng, Nguyễn Thị Phương, Đinh Văn Thức, Trần Đức Hùng, Nguyễn Trọng Nghĩa*, Nguyễn Hồng Liên, (2019), "Khảo sát cấu trúc và tính chất phân tử của 2,4,4’-triclobiphenyl & các sản phẩm hydrodeclo hóa bằng phương pháp phiếm hàm mật độ", Tạp chí Hấp phụ và Xúc tác Việt Nam, T.57, N4e3,4, tr.92-97. CT3. Nguyễn Quang Thắng, Nguyễn Thị Phương, Chu Thị Hải Nam, Tô Văn Thiệp, Nguyễn Hồng Liên*, (2020), "Ảnh hưởng của chất mở rộng mao quản đến cấu trúc vật liệu cacbon mao quản trung bình trật tự", Tạp chí Hóa học, T.5E12, N1, tr.235-240. CT4. 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