Luận án Tổng hợp vật liệu Composite trên cơ sở g-C₃N₄, ứng dụng trong điện hóa và quang xúc tác

Khả năng tái sử dụng TiO2/g-C3N4 Việc tái sử dụng hiệu quả chất xúc tác sau phản ứng quang hóa được xem là yêu cầu quan trọng cùng với hoạt tính xúc tác cao. Chất xúc tác đã qua sử dụng được tách ra bằng cách nung trong không khí ở 500 oC trong 3 giờ trước khi sử dụng lại. Hình 3.36 cho thấy sự thay đổi của hiệu suất phân hủy MB sau ba lần tái sử dụng. Sau mỗi lần sử dụng, hiệu suất giảm khoảng 6% so với lần sử dụng trước. Giản đồ XRD của chất xúc tác là không thay đổi, cho thấy chất xúc tác hiện tại là ổn định và có triển vọng trong xử lý nước thải phẩm màu. Hoạt tính quang xúc tác phân hủy một số chất màu trên TiO2/g-C3N4 Để khẳng định khả năng làm mất màu quang hóa dưới bức xạ khả kiến của vật liệu TiO2/g-C3N4, chúng tôi cũng tiến hành thêm các thí nghiệm khảo sát với ba chất màu hữu cơ có cấu trúc hóa học khác so với MB là Malachite Green (MG), Methyl Blue (MyB) và Methyl Red (MR) (Hình .37). Việc đánh giá sự phân hủy chất màu dựa vào sự thay đổi cường độ peak hấp thụ chính của MG, MyB và MR ở (MG) = 617 nm, (MyB) = 6 7 nm và (MR) = 521 nm. Kết quả khảo sát (Hình .38) cho thấy vật liệu TiO2/g-C3N4 thể hiện khả năng xúc tác hiệu quả trong việc phân hủy các chất màu hữu cơ khác nhau. Hiệu suất khử màu quang hóa các chất màu MG (chất màu cation) sau 8 phút chiếu sáng là 1 %, MyB (chất màu anion) sau chiếu sáng 1 phút là 7,8 % và MR (chất màu trung hòa) sau 120 phút chiếu sáng là 6 , %.

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tính xúc tác tuyệt vời đối với phân hủy Methylene Blue trong vùng ánh sáng khả kiến. goài ra, TiO2/g-C3N4 cũng thể hiện sự phân hủy chất xúc tác quang hiệu quả đối với các thuốc nhuộm có bản chất khác nhau như Malachite Green(chất màu cation), Methyl Blue (chất màu anion) và Methyl Red (chất màu trung hòa). Do tính chất thân thiện với môi trường và khả năng tái sinh khá cao, vật liệu TiO2/g-C3N4 có tiềm năng trong việc xử lý nước thải chứa các chất màu hữu cơ khó phân hu . 2. Kiến nghị Từ các kết quả nghiên cứu của luận án, chúng tôi rút ra một số kiến nghị như sau: - Phát triển vật liệu điện cực biến tính thành các điện cực in để có thể đo trực tiếp tại hiện trường. - Phát triển vật liệu xúc tác quang trong phân tích các hợp chất hữu cơ khó phân hủy. 111 DANH MỤC CÁC CÔNG TRÌNH CÔNG B KẾT QUẢ NGHIÊN CỨU C A LUẬN ÁN I. Tạp chí trong nước 1. Đặng Thị Ngọc Hoa, guyễn Thị Thanh Tú (2020), ghiên cứu tổng hợp vật liệu TiO2/g-C3N4 làm xúc tác quang hóa phân hủy xanh methylen trong vùng ánh sáng khả kiến, Tạp chí úc tác và hấp phụ iệt Nam, tập , số , tr.21-26, 20/9/2020. 2. Đặng Thị Ngọc Hoa, Nguyễn Thị Thanh Tú, Lê Thị Kim Dung (2021), ghiên cứu tổng hợp vật liệu composite -67/Fe2O3/g-C3N4 và ứng dụng, Tạp chí hoa học và công nghệ, Trường ại học Khoa học, ại học Huế, tập 18, số 2, 2 21. 3. Đặng Thị Ngọc Hoa, guyễn Đức Hồng (2022), Tổng hợp phức titanium peroxyde và khảo sát hoạt tính xúc tác của hệ TiO2/g-C3N4, Tạp chí hoa học ại học ế: hoa học tự nhiên, số 131-1A-2 22 (đã nhận đăng). II. Tạp chí quốc tế (ISI) 4. 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