- Tổng hợp thành công hệ vật liệu từ tính spinel ferrite Cu-MgFe2O4
bằng phương pháp đồng kết tủa. Vật liệu spinel của 2 ion kim loại
Cu0.5Mg0.5Fe2O4 có từ độ bão hòa 23,1 emu/g, cấu trúc đồng đều với kích
thước hạt trung bình 29,5 nm, hình thành đơn pha spinel khi nung ở 900 oC và
có diện tích bề mặt cũng như tính chất xốp cao hơn so với vật liệu spinel
ferrite CuFe2O4 và MgFe2O4.
- Nghiên cứu khả năng hấp phụ ion kim loại Pb2+ của vật liệu spinel
ferrite Cu0.5Mg0.5Fe2O4. Khi thay thế Mg2+ vào cấu trúc của CuFe2O4 đã làm
cải thiện dung lượng hấp phụ Pb2+ của CuFe2O4. Quá trình hấp phụ Pb2+ của
vật liệu Cu0.5Mg0.5Fe2O4 tuân theo mô hình đẳng nhiệt Langmuir và động học
biểu kiến bậc 2. Dung lượng hấp phụ Pb2+ cực đại của vật liệu
Cu0.5Mg0.5Fe2O4 là 57,44 mg/g ở pH = 7 và T = 25 oC. Vật liệu
Cu0.5Mg0.5Fe2O4 có tính hấp phụ chọn lọc, tương đối bền và ổn định đối với
sự hấp phụ loại bỏ Pb2+, có khả năng tái sử dụng tốt và dễ dàng thu hồi sau
mỗi chu kỳ sử dụng.
- Tổng hợp thành công vật liệu TiO2 và vật liệu tổ hợp
Cu0.5Mg0.5Fe2O4/TiO2 bằng phương pháp sol-gel. Giá trị năng lượng vùng
cấm của vật liệu tổ hợp Cu0.5Mg0.5Fe2O4/TiO2 là 2,86 eV so với 3,25 eV của
TiO2, sự phân tách điện tử của vật liệu Cu0.5Mg0.5Fe2O4/TiO2 tốt hơn so với
vật liệu TiO2 và Cu0.5Mg0.5Fe2O4, do đó đã thể hiện hoạt tính xúc tác quang
hóa tốt. Vật liệu tổ hợp Cu0.5Mg0.5Fe2O4/TiO2 có từ độ bão hòa là 11,2 emu/g ,
có khả năng tái sử dụng tốt và dễ dàng thu hồi sau mỗi chu kỳ sử dụng.
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PHỤ LỤC
Phụ lục 1: Phổ XRD lần lượt của các mẫu Cu0.5Mg0.5Fe2O4 nung ở
400÷1000
o
C trong 2 giờ; MgFe2O4; CuFe2O4; TiO2 và Cu0.5Mg0.5Fe2O4/TiO2.
160
161
162
163
164
Phụ lục 2: Phổ khối MS và sắc ký đồ của các mẫu RhB tại các thời
điểm khác nhau: 0 phút; 60 phút, 120 phút, 180 phút.
RhB: 443
165
DER: 415
166
EER, DR: 387
167
ER: 359
168
Phụ lục 3: Sắc đồ đo TOC của các mẫu RhB tại các thời điểm khác
nhau (a) 0 phút; (b) 30 phút; (c) 60 phút; (d) 90 phút; (e) 120 phút; (f) 150
phút và (g) 180 phút.
169
170
171
Phụ lục 4: Đường chuẩn phân tích Pb2+