Luận án Study on the hydroformylation of ethylene with co and CO₂ using supported ionic liquid phase silp/TiO₂ and nano Au/TiO₂ (SiO₂) catalyst

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Catal., A, 191, 153−162, 2000. DOI: 10.1016/j.jcat.2023.115248. 126 LIST OF PUBLICATIONS 1. Duc Duc Truong, Phuong Thi Mai Pham, Evgenii V. Kondratenko and Minh Thang Le. Au/SiO2-Based Catalysts for Propanol/Propanal Synthesis from CO2, C2H4, and H2 in a Dual-reactor System. ACS Sustainable Chem. Eng. 2022, 10, 50, 16548–16554. 2. Trương Dực Đức, Nguyễn Trung Huy, Lê Minh Thắng. Nâng cao hoạt tính xúc tác Au/SiO2 trong phản ứng chuyển hóa trực tiếp CO2, C2H4 và H2 thành propanol trên hệ hai thiết bị phản ứng nối tiếp. Tạp chí xúc tác và hấp phụ Việt Nam, 2020, Volume 9, p. 82-87. 3. Truong Duc Duc, Dinh Phuc Kien, Le Minh Thang. Performance of supported ionic liquid phase and nano gold catalystsover titania support for hydroformylation of ethylene. Tạp chí xúc tác và hấp phụ Việt Nam, 2019, Volume 8, p. 107-112. 4. Truong Duc Duc, Le Minh Thang. The formation of Rh-complexes and deactivation of supported ionic liquid phase (SILP) catalysts in hydroformylation of ethylene. Tạp chí xúc tác và hấp phụ Việt Nam, 2018, Volume 7, p. 37-43. 5. Truong Duc Duc, Le Minh Thang. Effects of synthesis methods on particle sizes of gold over titania support and catalytic activities in conversion of ethyelene into propanol with CO and H2. Tạp chí Hóa học, 2018, Volume 56, p. 479-483. 6. Van Chuc Nguyen, Van Hung Do, Duc Duc Truong, Anders Riisager, Rasmus Fehrmann, Minh Thang Le. The influence of supports on Rh-TPPTS supported ionic liquid-phase catalysts for the hydroformylation of ethylene. Chemistry Select, Volume 6, Issue 37, 2021, p. 9888-9893. 127 APPENDIX Appendix 1: SEM images of 0,5Au/TiO2 catalysts prepared by different procedures  All samples contained amorphous phases Figure A. 1. SEM images of the fresh 0.5Au/TiO2 catalysts prepared by different methods Appendix 2: Additional TEM images of catalysts Figure A. 2. TEM images of the fresh 1Au/SiO2 catalysts which is observed in different points. Figure A. 3. TEM images of the fresh 1Au/SBA-15 catalysts which is observed in different points. Figure A. 4. TEM images of the fresh 2Cs1Au/SiO2 catalysts which is observed in different points. 0.5Au/TiO2 QT1 0.5Au/TiO2 QT2 0.5Au/TiO2 QT3 0.5Au/TiO2 QT4 128 Figure A. 5. TEM images of the fresh 2Co1Au/SiO2 catalysts which is observed in different points. Appendix 3: Additional EPR spectra of catalysts Figure A. 6. EPR spectra of 0,2Rh-L/Rh=10-IL=5%-TiO2 fresh and spent (after deactivation). Figure A. 7. EPR spectra of 0,2Rh-L/Rh=10-IL=10%-TiO2 fresh and spent (after deactivation). -500000 0 500000 0 2000 4000 6000 8000Int en sity G fresh -1000000 0 1000000 2000000 0 2000 4000 6000 8000 Int en sity G spent -500000 0 500000 0 2000 4000 6000 8000Int en sity G fresh -1000000 0 1000000 0 2000 4000 6000 8000Int en sity G spent 129 Appendix 4: Catalyst stability Figure A. 8. Catalytic activity of 2AuSiO2 on reaction time in dual- reactor mode at 2MPa, contact time of 50 g.min.L-1 , temperature of the first reactor was kept constantly of 650oC, nominal feedstock of CO2/H2/C2H4/N2 = 1/1/1/1. Figure A. 9. Catalytic activity of 4Cs2AuSiO2 on reaction time in dual- reactor mode at 2MPa, contact time of 50 g.min.L-1 , temperature of the first reactor was kept constantly of 650oC, nominal feedstock of CO2/H2/C2H4/N2 = 1/1/1/1. Figure A. 10. Catalytic activity of 4Ce2Cs2AuSiO2 on reaction time in dual- reactor mode at 2MPa, contact time of 50 g.min.L-1 , temperature of the first reactor was kept constantly of 650oC, nominal feedstock of CO2/H2/C2H4/N2 = 1/1/1/1.