Báo cáo Nghiên cứu tổng hợp vật liệu bentonit biến tính, ứng dụng hấp phụ phốtpho trong nước

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Zuo S, Zhou R, Chenze QI (2011), Synthesis and characterization of aluminum and Al/REE pillared clays and supported palladium catalysts for benzene oxidation, Journal of Rare Earthes, Vol. 29, No. 1, 52 – 57. 129 CÁC BÀI BÁO CÔNG BỐ LIÊN QUAN ĐẾN CÔNG TRÌNH 1. Lê Bá Thuận, Bùi Văn Thắng, Nguyễn Mạnh Trường, Trần Văn Sơn, Thân Văn Liên (2010), Nghiên cứu hấp phụ phốtpho trong dung dịch nước bằng vật liệu bentonit biến tính lantan, Tạp chí Hoá học, T.48, 4C, 384 – 389. 2. Lê Bá Thuận, Bùi Văn Thắng, Trần Văn Sơn (2010), Nghiên cứu công nghệ xử lý phú dưỡng nước hồ Hoàn Kiếm bằng vật liệu bentonit biến tính lantan, Tạp chí Hoá học, T.48, 4C, 402 – 407. 3. Lê Bá Thuận, Bùi Văn Thắng, Trần Văn Sơn (2011), Nghiên cứu điều chế, tính chất của vật liệu La/Al chống bentonit và ứng dụng hấp phụ phốtphat trong nước. Phần I. Nghiên cứu điều chế, tính chất của vật liệu, Tạp chí Hoá học, T.49, 3A, 302 – 406. I PHẦN PHỤ LỤC Phụ lục P1. KẾT QUẢ PHÂN TÍCH XRD CỦA B40-La A1. KẾT QUẢ PHÂN TÍCH XRD CỦA MẪU B40-La Ở TỶ LỆ CỦA LaCl3/B40 KHÁC NHAU Fa cul ty o f Che m istry, V NU, D8 A DV ANCE -B ruker - MB 1 O pe ra tion s: Sm o oth 0 .60 0 | Im p o rt 1) F ile : Tha ng V C N X H MB 1. raw - Ty p e: L oc ke d C ou pl ed - S tar t: 1 .00 0 ° - E n d: 1 5.0 00 ° - Ste p: 0 .02 0 ° - S t e p tim e: 0.5 s - Te mp .: 2 5 °C ( R o om ) - T im e Star ted : 13 s - 2-T he ta: 1 .00 0 ° - T h e ta : 0.5 00 ° - C h i: 0.0 0 L ef t A ng le : 3 .40 0 ° - R igh t An g le: 8 .40 0 ° - L e ft I n t.: 1 16 C p s - R ig ht In t. : 8 6.4 C ps - Ob s. M a x : 5.7 73 ° - d ( Ob s. M a x ): 15 . 2 95 - Ma x Int .: 17 0 C p s - N e t H ei gh t: 67 .7 Cp s - FW H M : 1 .87 3 ° - C ho rd M id .: 5.8 L in ( C ps ) 0 10 20 30 40 50 60 70 80 90 10 0 11 0 12 0 13 0 14 0 15 0 16 0 17 0 18 0 19 0 20 0 21 0 22 0 23 0 24 0 25 0 26 0 27 0 28 0 29 0 30 0 2-Theta - Scale 1.1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 d = 1 5 .1 1 7 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La0.25 B40-L 0.25.raw - Typ : Locked Coupled - Start: 1.000 ° - End: 15.000 ° - Step: 0.020 ° - St p time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 13 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0.00 L in ( C ps ) d = 1 5 .1 1 7 Faculty of Chem istry, VNU, D8 ADVANCE-Bruker - MB2 1) File : Thang V CNX H MB 2.raw - Type: Locked Coupled - S tar t: 1 .000 ° - E nd: 15.000 ° - Step: 0 .020 ° - S tep tim e: 0.5 s - Temp .: 2 5 °C (Room ) - Tim e S tar ted : 6 s - 2 -Theta : 1.000 ° - Theta: 0 .500 ° - C hi: 0 .00 ° Left A ng le: 3 .680 ° - R igh t Ang le: 8 .360 ° - Le ft In t.: 125 Cps - Right In t.: 91.5 Cps - Ob s. Max: 5.860 ° - d (Ob s. Max): 15.070 - Max Int.: 181 Cp s - Net Hei ght : 71 .3 Cps - FW HM : 1 .57 5 ° - Chord Mid .: 5.8 L in ( C p s) 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 2-Theta - Scale 1.1 2 3 4 5 6 7 8 9 10 11 12 13 14 d = 1 5 .3 2 5 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La0.35 .r - T : ked upled - tart: 1. 00 ° - n : 1 .000 ° - te : t . L in ( C p s) d = 1 5 .3 2 5 II F a c u lty o f C h e m is tr y , V N U , D 8 A D V AN C E -B ru ke r - M B 3 1) F ile : T h a ng V CN X H M B 3 .r aw - T yp e : L o ck e d C ou p l e d - S ta r t: 1 . 00 0 ° - E n d : 1 5 .0 0 0 ° - S te p : 0 .0 2 0 ° - S te p t im e: 0 .5 s - T e m p . : 2 5 ° C ( R o o m ) - T im e S ta r ted : 5 s - 2 -T h e ta : 1 .0 0 0 ° - T he ta : 0 . 50 0 ° - C hi: 0 .0 0 ° L e f t A ng le : 4 .6 2 0 ° - R igh t An g le : 7 .2 4 0 ° - L e ft In t .: 1 0 2 C p s - R ig ht In t. : 7 0 .3 C p s - O b s . M a x : 5. 5 40 ° - d (O b s. M a x ): 1 5 .9 3 9 - M a x In t . : 1 1 7 C p s - N e t H ei gh t : 26 .3 C p s - F W H M : 1 .17 0 ° - C h o rd M id . : 5 .6 Li n (C p s ) 0 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 1 0 0 1 1 0 1 2 0 1 3 0 1 4 0 1 5 0 1 6 0 1 7 0 1 8 0 1 9 0 2 0 0 2 1 0 2 2 0 2 3 0 2 4 0 2 5 0 2 6 0 2 7 0 2 8 0 2 9 0 3 0 0 2 -T h eta - S c a le 1.1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 d = 1 6 .0 84 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La0.50 File: ThangVCNXH B40-La0.50.raw - Type: Locked Coupled - Start: 1.000 ° - End: 15.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (R om) - Time Started: 5 s - 2-Theta: . 0 ° - - i: .0 ° Li n (C p s ) d = 1 6 .0 84 F aculty o f C hem is try , V NU , D8 A D V AN CE -B ru ke r - M B 4 1) F ile : Tha ng V CN X H M B 4.r aw - T yp e: L ock e d C ou pl ed - S tar t: 1 . 00 0 ° - E n d: 1 5.0 00 ° - S te p: 0 .02 0 ° - S te p t im e: 0.5 s - T e mp .: 2 5 °C ( R o om ) - T im e S tar ted : 5 s - 2 -T h eta : 1.0 00 ° - T he ta: 0 . 50 0 ° - C hi : 0 .00 ° L eft A ng le : 4 .40 0 ° - R igh t An g le: 6 .92 0 ° - L e ft In t.: 1 01 C p s - R ig ht In t. : 7 6.2 C ps - Ob s . M a x : 5. 4 80 ° - d (Ob s. M a x ): 16 .1 14 - M a x Int. : 11 3 C p s - N e t H ei gh t : 22 .2 C p s - F W H M : 1 .17 8 ° - C ho rd M id .: 5 .5 L in ( C p s) 0 10 20 30 40 50 60 70 80 90 10 0 11 0 12 0 13 0 14 0 15 0 16 0 17 0 18 0 19 0 20 0 21 0 22 0 23 0 24 0 25 0 26 0 27 0 28 0 29 0 30 0 2-Theta - S c ale 1.1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 d = 1 6 .2 8 6 Faculty of Chemistry, VNU, D8 ADVANCE-Bruke – B40-La0.75 : n B40-La0.75.raw - Type: Locked Coupled - Start: 1.000 ° - End: 15.000 ° - Step: .020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time S arted: 5 s - 2-Theta: 1.000 ° - Theta: 0.5 0 ° - Chi: 0. 0 ° L in ( C p s) d = 1 6 .2 8 6 F a cu l ty o f C h e m is tr y , V N U , D 8 A D V A N C E -B ru ke r - M B 5 O pe ra t ion s : S m o o th 0 .60 0 | I m p o rt 1 ) F ile : T h a ng V C N X H M B 5 . r aw - T y p e: L oc k e d C ou pl e d - S t ar t: 1 .00 0 ° - E n d: 1 5.0 00 ° - S te p : 0 . 02 0 ° - S te p t im e : 0. 5 s - T e m p . : 2 5 ° C ( R o om ) - T im e S ta r te d : 5 s - 2 -T h e ta : 1 .0 0 0 ° - T h e ta : 0 .5 0 0 ° - C hi : 0 .0 0 ° L e f t A n g le : 4 .1 2 0 ° - R ig h t A n g le : 7 .3 8 0 ° - L e ft I n t .: 1 24 C p s - R ig h t I n t. : 8 2.3 C ps - O b s . M a x : 5 .5 8 0 ° - d ( O b s . M a x ): 15 . 8 25 - M a x Int . : 14 5 C p s - N e t H ei g h t : 40 .1 C p s - F W H M : 1 .66 6 ° - C h o rd M id . : 5 .7 L in ( C p s) 0 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 1 0 0 1 1 0 1 2 0 1 3 0 1 4 0 1 5 0 1 6 0 1 7 0 1 8 0 1 9 0 2 0 0 2 1 0 2 2 0 2 3 0 2 4 0 2 5 0 2 6 0 2 7 0 2 8 0 2 9 0 3 0 0 2 - T h e t a - S c a le 1. 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 d =1 5 .9 5 3 istry, VNU, D8 ADVANCE-Bruker – B40-La1.00 B40-L 1.00.raw - Type: Locked Coupled - Start: 1.000 ° - End: 15.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 5 s - 2-Theta: 1.000 ° - Theta: .500 ° - Chi: .00 ° L in ( C p s) d= 1 5 .9 5 3 III A2. KẾT QUẢ PHÂN TÍCH XRD CỦA MẪU B40-La ĐƯỢC ĐIỀU CHẾ Ở pH KHÁC NHAU Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MBpH5 File: ThangVCNXH MBpH 5.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Tem p.: 25 °C (Room) - Time Star ted: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0.0 L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d = 1 5 .3 75 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LapH5 B40-LapH5.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0.0 L in ( C p s) d = 1 5 .3 75 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MBpH6 File: ThangVCNXH MBpH 6.raw - Type: Lo cked Co upled - Start: 1.000 ° - End : 20 .000 ° - Step: 0.020 ° - Step time: 0.5 s - Tem p.: 25 °C (Roo m) - Time Star ted: 5 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0 .0 L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 2 0 d = 15 .8 4 2 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LapH6 il : B40-LapH6.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 5 s - 2-Theta: 1.000 ° - Theta: .500 ° - Chi: 0.0 L in ( C p s) d = 15 .8 4 2 IV F a c u l ty o f C h e m is tr y , V N U , D 8 A D V A N C E -B ru k e r - M B p H 9 F ile : T h a ng V C N X H M B p H 9 . ra w - T y p e: L o c k e d C o u ple d - S ta rt : 1 . 0 0 0 ° - E n d : 2 0 .0 0 0 ° - S te p : 0 .0 2 0 ° - S te p t im e : 0 . 5 s - T em p. : 2 5 ° C ( R o o m ) - T im e S ta r te d : 6 s - 2 -T h e ta : 1 . 0 0 0 ° - T he ta: 0 .5 0 0 ° - C h i: 0 .0 L in ( C p s) 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 2 - T h e ta - S c a le 1 2 3 4 5 6 7 8 9 10 1 1 1 2 13 1 4 1 5 1 6 17 1 8 1 9 2 0 d =1 5 .4 1 7 aculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LapH7 B40-LapH7.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 . 00 ° - Step: 0. 20 ° - Step time: 0.5 s - Temp.: 25 °C (R om) - Time Started: 6 s - 2-Theta: 1.000 ° - : L in ( C p s) d =1 5 .4 1 7 F aculty o f C hem is try , V NU , D8 A D V AN CE -B ru ke r - M B pH 8 File : Tha ng V CN X H M B pH 8.ra w - Typ e: Lo c ke d C o u ple d - S ta rt : 1 .0 0 0 ° - E nd : 20 .00 0 ° - S te p: 0 .0 2 0 ° - S tep t im e : 0.5 s - T em p.: 2 5 °C ( R oo m ) - T im e S tar te d : 1 2 s - 2- The ta: 1 .0 0 0 ° - Th eta : 0.5 00 ° - C h i: 0 . L in ( C p s) 0 10 0 20 0 30 0 40 0 50 0 2-Theta - S c ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d = 15 .4 5 8 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LapH8 B40-LapH8.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time S arted: 12 s 2-Theta: 1. 00 ° - Theta: 0.500 ° - Chi: 0. L in ( C p s) d = 15 .4 5 8 F a cu lty o f C h e m is tr y , V N U , D 8 A D V AN C E -B ru ke r - M B pH 7 F ile : T ha ng V CN X H M B pH 7 .ra w - T yp e: Lo c ke d C o u ple d - S ta rt : 1 .0 0 0 ° - E nd : 20 .00 0 ° - S te p : 0 .0 2 0 ° - S tep t im e : 0.5 s - T em p.: 2 5 °C ( R oo m ) - T im e S ta r te d : 7 s - 2 -T h e ta : 1 .00 0 ° - T he ta: 0 .5 0 0 ° - C h i: 0 .0 L in ( C p s) 0 10 0 20 0 30 0 40 0 50 0 2-T h eta - S c ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d = 1 5 .2 1 2 d = 8 .5 04 d =4 .8 1 0 d = 4. 4 8 7 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LapH9 B40-LapH7.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 7 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: .0 L in ( C p s) d = 1 5 .2 1 2 d = 8 .5 04 d =4 .8 1 0 d = 4. 4 8 7 V A3. KẾT QUẢ PHÂN TÍCH XRD CỦA MẪU B40-La ĐƯỢC ĐIỀU CHẾ Ở NHIỆT ĐỘ KHÁC NHAU Faculty o f Chemistry, VNU, D8 ADVANCE-Bruker - MBT50 File : Tha ng VCNXH MBT50 .ra w - Type : Locked Co uple d - Start : 1.000 ° - E nd : 20 .00 0 ° - S tep: 0.0 20 ° - S tep time : 0.5 s - Tem p.: 2 5 °C (R oom) - Time S ta rte d: 6 s - 2-The ta : 1 .000 ° - T he ta: 0.5 00 ° - Ch i: 0.0 L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d = 1 5 .3 3 4 d = 5 .5 9 4 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LaT50 B40-LaT50.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time S arted: 6 s 2-Theta: 1. 00 ° - Theta: 0.500 ° - Chi: .0 L in ( C p s) d = 1 5 .3 3 4 d = 5 .5 9 4 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MBT70 File: ThangVCNXH MBT70.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Tem p.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1 .000 ° - T heta: 0.500 ° - Chi: 0.0 L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d = 1 5 .5 0 0 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker –B40-LaT70 B40-LaT70.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: .020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0.0 VI Faculty o f Chemistry, VNU, D8 ADVANCE-Bruke r - MBT90 File : ThangVCNX H M BT90 .ra w - Type : Locked Coupled - Sta rt: 1.000 ° - E nd : 20 .000 ° - Step: 0.020 ° - S tep time : 0.5 s - Tem p.: 25 °C (R oom) - Time Started: 5 s - 2-The ta : 1 .000 ° - T he ta: 0.500 ° - Ch i: 0.0 L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d = 15 .8 4 2 d = 5. 5 9 4 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-LaT90 il : g XH B40-LaT90.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 5 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0.0 L in ( C p s) d = 15 .8 4 2 d = 5. 5 9 4 A4. KẾT QUẢ PHÂN TÍCH XRD CỦA MẪU B40-La ĐƯỢC ĐIỀU CHẾ Ở NỒNG ĐỘ HUYỀN PHÙ KHÁC NHAU Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MB15% File: ThangVCNXH MB15%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Tem p.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0. L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d= 1 5 .2 1 2 t f i try, , 8 A A CE-Bruker – B40-La2.5% il : B40-La2.5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0. L in ( C p s) d= 1 5 .2 1 2 VII F a cu l ty o f C he m istr y, V N U , D 8 A D V A N C E -B ru ke r - M B 5% F ile : T h a n g V C NX H M B 5% .r aw - T y p e : L o ck e d C ou pl e d - S ta rt : 1 .0 0 0 ° - E n d: 20 .0 0 0 ° - Ste p : 0 .0 2 0 ° - S te p t im e : 0.5 s - T e m p . : 2 5 ° C ( R oo m ) - T im e S ta r ted : 6 s - 2 -T h eta : 1.0 00 ° - T he t a: 0 . 50 0 ° - C hi: 0 .0 L in ( C p s ) 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 2 -T h eta - S c a le 1 2 3 4 5 6 7 8 9 1 0 1 1 1 2 1 3 1 4 1 5 16 17 1 8 1 9 2 0 d = 1 5 .0 13 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La5% i B40-La5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: .020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: .500 ° - Chi: 0.0 L in ( C p s ) d = 1 5 .0 13 F a c u l ty o f C h e m is tr y , V N U , D 8 A D V A N C E -B ru ke r - M B 7 . 5% F ile : T ha ng V C N X H M B 7,5 % . ra w - T y p e : Lo c k ed C o up le d - S ta rt : 1.0 0 0 ° - E n d : 2 0.0 0 0 ° - S te p : 0.0 20 ° - S te p t im e : 0 .5 s - T e m p . : 25 ° C (R o o m ) - T im e S ta rte d : 1 7 s - 2 -T h eta : 1.0 0 0 ° - T he ta: 0 .5 0 0 ° - C h i: L in ( C p s) 0 1 0 0 2 0 0 3 0 0 4 0 0 5 0 0 2 - T h e t a - S c a le 1 2 3 4 5 6 7 8 9 10 1 1 1 2 13 14 1 5 1 6 17 1 8 19 2 0 d = 15 .6 69 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La . File: ThangVCNXH B40-La7,5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 17 s - 2-Theta: 1. 00 ° - Theta: .500 ° - Chi: L in ( C p s) d = 15 .6 69 F a culty o f C h e m is tr y , V NU , D8 A D V AN CE -B ru ke r - M B 10 % F ile : T ha ng V CN X H M B 10 % .ra w - T y pe : Lo ck e d Co up le d - Sta rt : 1.0 00 ° - E nd : 2 0 .0 0 0 ° - S tep : 0 .0 20 ° - S te p ti m e : 0 .5 s - T em p.: 25 °C (R o o m ) - T im e Sta r te d: 6 s - 2- T he ta : 1 . 00 0 ° - T h e ta : 0.5 00 ° - C h i: 0. L in ( C p s) 0 10 0 20 0 30 0 40 0 50 0 2-Th eta - S c ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d = 1 5 .5 0 0 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La10 il : B40-La10%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 .000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - Chi: 0. L in ( C p s) d = 1 5 .5 0 0 VIII Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MB2.5% File : Thang VCNXH MB2,5%.raw - Type : Lo cked Coup led - S tart: 1.000 ° - End : 20.00 0 ° - S tep : 0.020 ° - Step tim e: 0 .5 s - Tem p.: 25 °C (Room) - Time Sta rted: 5 s - 2-Theta: 1 .000 ° - Theta : 0.500 ° - Chi: 0. L in ( C p s) 0 100 200 300 400 500 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 1 5 16 17 18 19 2 0 d = 1 5 .5 0 0 lty of hemistry, VNU, D8 ADVANCE-Bruker – B40-La15% B40-La15%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 2 . 00 ° - Step: 0. 20 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 5 s - 2-Theta: 1. 0 ° - Theta: 0.5 0 ° - Chi: 0. L in ( C p s) d = 1 5 .5 0 0 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MMT-La3+ (1:0.25) pH = 8 File: ThangVCNX H MMT-La(1-0,25)pH=8.raw - Type: Locked Coupled - S tar t: 1.000 ° - End: 20.000 ° - S tep: 0 .020 ° - Step tim e: 0.5 s - Temp .: 25 °C (Room ) - Time Sta rted: 6 s - 2-T heta: 1.000 ° - Th eta : 0. L in ( C p s) 0 100 200 300 400 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d = 1 5 .2 9 7 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B40-La20% l : B40-La30%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: .020 ° - Step time: 0.5 s - T mp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: . L in ( C p s) d = 1 5 .2 9 7 IX PHỤ LỤC 2. KẾT QUẢ PHÂN TÍCH XRD CỦA MỘT SỐ MẪU ĐẶC TRƯNG CỦA B90-La F aculty of Chem istry, VNU , D8 A DVAN CE -Bruke r - La -M MT 0 .35 File : Tha ng V CNX H La -M MT 0 ,35 .ra w - Type : Lo cked Co up le d - S ta rt: 1.0 00 ° - En d : 2 0. 0 0 0 ° - S tep : 0. 0 20 ° - Ste p tim e : 0 .5 s - Te m p.: 25 °C (Ro o m) - Tim e Sta rte d: 6 s - 2- The ta: 1 .0 0 0 ° - Th eta : 0.5 00 ° - C L in ( C p s) 0 10 0 20 0 30 0 40 0 50 0 2-Theta - Sc ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d= 1 5 .4 42 il B90-La0.35.raw - Type: Locked Coupled - Start: 1.00 ° - End: 20.00 ° - Step: 0.010 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° Faculty of Chemistry, VNU, D8 DVANCE-Bruker – B90-La0.35 L in ( C p s) d= 1 5 .4 42 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker - MMT:La3+ = 1:0.5 File: ThangVCNXH MMT-La(1-0,5).raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.010 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° - L in ( C p s) 0 100 200 300 400 2-Theta - Scale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 d= 1 5 .1 7 2 ile: ThangVCNXH B90-La0.50.raw - y : oupled - Start: 1. 00 ° - End: 20. 00 ° - Step: 0.010 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.500 ° Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B90-La0.50 L in ( C p s) d= 1 5 .1 7 2 X F a culty o f C he m istr y, V N U , D8 A D V AN CE -B ru ke r - La -M M T 0 .75 F ile : T ha ng V C NX H La -M M T 0, 75 .ra w - T ype : Lo c ked C o up le d - S ta rt : 1 .0 00 ° - En d : 20. 0 00 ° - S tep : 0.0 20 ° - Ste p t im e : 0 .5 s - Te m p.: 25 °C (R o o m ) - T i m e Sta rte d: 6 s - 2 -T he ta : 1 .0 0 0 ° - T h et a : 0 .5 00 ° - C L in ( C p s ) 0 10 0 20 0 30 0 40 0 50 0 2-Theta - S c ale 1 2 3 4 5 6 7 8 9 10 11 12 13 14 1 5 16 17 1 8 19 20 d = 1 5 .0 8 3 Faculty of Chemistry, E-Bruker – B90-LapH7 B90-LapH7.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20. 0 ° - Step: 0.02 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 6 s - 2-Theta: 1.000 ° - Theta: 0.50 ° - C L in ( C p s ) d = 1 5 .0 8 3 F a cu l ty o f C h e m is tr y , V N U , D 8 A D V A N C E -B ru ke r - M M T -L a 3 + (1 : 0 .2 5 )4 0 C F ile : T ha ng V C N X H M M T -L a( 1 -0 ,2 5 )4 0 C .ra w - T yp e : L o ck ed C o up le d - S ta rt : 1 .0 00 ° - En d : 2 0 .0 0 0 ° - S te p : 0 .0 2 0 ° - S te p t im e : 0 . 5 s - T e m p. : 25 ° C (R o o m ) - T i m e Sta rte d: 1 2 s - 2 - T h e ta : 1 .0 0 0 ° - T h e ta : 0 . L in ( C p s) 0 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 1 0 0 1 1 0 1 2 0 1 3 0 1 4 0 1 5 0 1 6 0 1 7 0 1 8 0 1 9 0 2 0 0 2 - T he ta - S c a le 1 2 3 4 5 6 7 8 9 1 0 11 1 2 13 1 4 1 5 16 17 1 8 1 9 2 0 d = 1 4 .8 4 1 Faculty of Chemistry, VNU, D8 ADVANCE Bruker – B90-LaT 0 ile: ThangVCNXH B90-T50.raw - Type: Locked C upled - Start: 1.000 ° - End: 20.000 ° - Step: 0.020 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - Time Started: 12 s - 2-Theta: 1.0 ° - Theta: 0. L in ( C p s) d = 1 4 .8 4 1 F a culty o f C he m istr y, V N U , D8 A DV A N CE -B ru ke r - M M T -La 3+ (1:0 .2 5 )60 C F ile : T ha ng V C N X H M M T -L a( 1-0 ,25 )6 0 C .ra w - T y pe : L o ck ed C o up le d - S ta rt : 1.0 00 ° - E n d : 2 0. 0 0 0 ° - S tep : 0. 0 20 ° - Ste p t im e : 0 .5 s - T e m p.: 25 °C (R o o m ) - T i m e Sta r te d: 6 s - 2- T he ta : 1 .0 0 0 ° - T h eta : 0 .5 L in ( C p s) 0 10 20 30 40 50 60 70 80 90 10 0 11 0 12 0 13 0 14 0 15 0 16 0 17 0 18 0 19 0 20 0 2 -The ta - S c a le 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d = 1 5 .2 2 1 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B90-LaT70 : angVCNXH B90-LaT70.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.02 ° - Step time: 0.5 s - Temp.: 25 °C (Room) - i : s - 2-Theta: 1. 0 ° - Theta: 0.5 L in ( C p s) d = 1 5 .2 2 1 XI F a cul ty o f C he m is tr y, V NU , D8 A DV A N CE -B ru ke r - MM T -La 3+ (1-0.2 5 ) 2 .5% File : Tha ng V C N X H M M T-L a( 1-0 ,25 )2 ,5% .raw - Ty p e: L oc k ed C ou p led - S tar t: 1 .00 0 ° - E n d: 2 0.0 00 ° - Ste p: 0 .02 0 ° - S te p t im e: 0 .5 s - Te m p .: 2 5 °C ( R o om ) - T im e S tar ted : 2 s - 2 -Th eta : 1 .0 00 ° - The ta : 0 . L in ( C p s) 0 10 20 30 40 50 60 70 80 90 10 0 11 0 12 0 13 0 14 0 15 0 16 0 17 0 18 0 19 0 20 0 21 0 22 0 23 0 24 0 25 0 26 0 27 0 28 0 29 0 30 0 2 -Theta - Sc ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d= 1 5. 5 58 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B9-La2.5% gVCNXH B90- 2,5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.000 ° - Step: 0.02 ° - Step time: 0.5 s - Temp.: 25 °C (Roo ) i rt : s - 2-Theta: 1. 0 ° - Theta: 0. L in ( C p s) d= 1 5. 5 58 F a culty o f C h e m is tr y , V NU , D8 A D V AN CE -B ru ke r - M M T -La 3+ (1-0.2 5 ) 5 % F ile : T ha ng V CN X H M M T -L a(1-0 ,25 )5 % .ra w - T y pe : Lo c ke d C o up le d - S ta rt : 1.0 00 ° - E nd : 2 0 .00 0 ° - S tep : 0 .0 20 ° - S tep ti m e : 0 .5 s - T em p.: 25 °C (R oo m ) - T im e S ta rte d: 6 s - 2- T he ta : 1 .00 0 ° - T h e ta : 0.5 0 L in ( C p s) 0 10 20 30 40 50 60 70 80 90 10 0 11 0 12 0 13 0 14 0 15 0 16 0 17 0 18 0 19 0 20 0 21 0 22 0 23 0 24 0 25 0 26 0 27 0 28 0 29 0 30 0 2-Th eta - S c ale 1 2 3 4 5 6 7 8 9 10 11 1 2 13 14 1 5 16 17 1 8 19 2 0 d = 1 5 .6 1 9 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B90-La5% gVCNXH B90-La5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.0 0 ° - Step: 0.02 ° - Step time: 0.5 s - Temp.: 25 °C (Roo i rted: 6 s - 2-Theta: 1. 0 ° - Theta: 0.50 L in ( C p s) d = 1 5 .6 1 9 F a c u l ty o f C h e m is tr y , V N U , D 8 A D V A N C E -B ru k e r - M M T -L a 3 + (1 - 0 .2 5 ) 7 .5 % F ile : T h a ng V C N X H M M T -L a ( 1 -0 ,2 5 )7 ,5% . r aw - T y p e : L o c k ed C ou p le d - S ta r t: 1 . 00 0 ° - E n d : 2 0 .0 0 0 ° - S te p : 0 .0 2 0 ° - S te p t im e: 0 .5 s - T e m p . : 2 5 ° C ( R o o m ) - T im e S ta r t ed : 6 s - 2 -T h e ta : 1 .0 0 0 ° - T he ta : 0 . L in ( C p s) 0 1 0 2 0 3 0 4 0 5 0 6 0 7 0 8 0 9 0 1 0 0 1 1 0 1 2 0 1 3 0 1 4 0 1 5 0 1 6 0 1 7 0 1 8 0 1 9 0 2 0 0 2 1 0 2 2 0 2 3 0 2 4 0 2 5 0 2 6 0 2 7 0 2 8 0 2 9 0 3 0 0 2 - T h e ta - S c a le 1 2 3 4 5 6 7 8 9 10 1 1 1 2 13 1 4 1 5 1 6 17 1 8 1 9 2 0 d = 15 .6 2 3 Faculty of Chemistry, VNU, D8 ADVANCE-Bruker – B90-La7. % ile: angVCNXH B90-La7,5%.raw - Type: Locked Coupled - Start: 1.000 ° - End: 20.0 0 ° - Step: 0.02 ° - Step time: 0.5 s - Temp.: 25 ° ( i Started: 6 s - 2-Theta: 1. 00 ° - Theta: 0. L in ( C p s) d= 15 .6 2 3 XII PHỤ LỤC 3. KẾT QUẢ PHÂN TÍCH XRD CỦA MỘT SỐ MẪU BAlLa 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlLa-14d L in ( C p s) File: ThangVCNXH BAlLa-14d.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .8 5 9 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlLa-21d L in ( C p s) File: ThangVCNXH BAlLa-21d.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .7 3 0 XIII 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlLa-OH-1.5 L in ( C p s) File: ThangVCNXH BAlLa-OH-1.5.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 7 .9 8 3 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlLa-OH-2.5 L in ( C p s ) File: ThangVCNXH BAlLa-OH-2.5.raw - Type: Locked Couplet - Start: 1.000o -End: 20.000o- Step: 0,020o - Step time: 0.5 s - Temp: 25oC (Room) - Time started: 12 s - 2-Theta: 1.000o - Theta: 0.500o- Chi: 2 - Theta - Scale d = 1 8 .8 5 9 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlLa-C25 L in ( C p s) File: ThangVCNXH BAlLa-C25.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .8 5 9 XIV PHỤ LỤC 4. KẾT QUẢ PHÂN TÍCH XRD CỦA MỘT SỐ MẪU BAlFe 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-1 L in ( C p s) File: ThangVCNXH BAlFe-1.raw - Type: Locked Couplet - Start: 1.000o -End: 20.000o- Step: 0,020o - Step time: 0.5 s - Temp: 25oC (Room) - Time started: 12 s - 2-Theta: 1.000o - Theta: 0.500o- Chi: 2 - Theta - Scale d = 1 6 .2 6 2 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 7 1 8 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chem is try, HU S, V NU , D 8 A DV A NC E -B rucke r - B AlFe -2 L in ( C p s) F ile: ThangVCNXH BAlFe-2.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step tim e: 0.5 s - Tem p: 25 o C (Room ) - Tim e started: 12 s - 2-Theta: 1.000 o - Theta: 0 .500 o - Chi: 2 - T heta - Scale d = 1 8 .1 7 1 XV 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 7 1 8 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Facu lty o f C hem istry, H US, VN U, D8 AD VANC E-Brucker - BA lFe-14d L in ( C p s ) File: ThangVCNXH BAlFe-14d.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0 ,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 18 .2 9 9 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-21d L in ( C p s) File: ThangVCNXH BAlFe-21d.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .1 0 1 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-C15 L in ( C p s ) File: ThangVCNXH BAlFe-C15.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 7 .8 4 1 XVI 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chem istry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-T50 L in ( C p s ) F ile: ThangVCNXH BAlFe-T50.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Tem p: 25 o C (Room) - Tim e started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .3 0 3 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-T70 L in ( C p s) File: ThangVCNXH BAlFe-T70.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 7 .5 0 9 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-OH-1.5 L in ( C p s) File: ThangVCNXH BAlFe-OH-1.5.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 7 .4 9 8 XVII 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 0 50 100 150 200 250 300 350 400 450 500 550 600 650 Faculty of Chem istry, HUS, VNU, D8 ADVANCE-Brucker - BAlFe-OH-2.5 L in ( C p s) File: ThangVCNXH BAlFe-OH-2.5.raw - Type: Locked Couplet - Start: 1.000 o -End: 20.000 o - Step: 0,020 o - Step time: 0.5 s - Temp: 25 o C (Room) - Time started: 12 s - 2-Theta: 1.000 o - Theta: 0.500 o - Chi: 2 - Theta - Scale d = 1 8 .0 0 5 Phụ lục P5 PHỔ HỒNG NGOẠI CỦA MỘT SỐ MẪU BENTONIT BIẾN TÍNH Ten mau: B90Date: 10/12/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.000 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.000 cm-1 A 3698 3626 3445 1638 1431 1035 780 704 639 532 471 Hình P3.1. Phổ hồng ngoại của mẫu B90 XVIII Ten mau: B40Date: 10/12/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.350 0.36 0.38 0.40 0.42 0.44 0.46 0.48 0.50 0.52 0.54 0.56 0.58 0.600 cm-1 A 3633 3424 1646 1435 1037 534 Hình P3.2. Phổ hồng ngoại của mẫu B40 TEN MAU: B40-LaDate: 10/13/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.150 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.600 cm-1 A 3699 3625 3429 1639 1488 1034 775 694 652 538 471 Hình P3.3. Phổ hồng ngoại của mẫu B40-La XIX Mail: sonhuco@yahoo.comResolution: 4cm-1 Ten mau: B90-LaDate: 10/12/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.300 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80 0.85 0.90 0.95 1.000 cm-1 A 3636 3412 1641 1475 1435 1035 791 711 637 578 529 Hình P3.4. Phổ hồng ngoại của mẫu B90-La TEN MAU: BAlLa-OH-2.spDate: 10/13/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.300 0.32 0.34 0.36 0.38 0.40 0.42 0.44 0.46 0.48 0.50 0.52 0.54 0.56 0.58 0.600 cm-1 A 3622 3471 1640 1491 1040 734 584 552 Hình P3.5. Phổ hồng ngoại của mẫu BAlLa XX TEN MAU: BAlFe-OH-2.spDate: 10/13/2011 4000.0 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000 800 600 400.0 0.100 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.600 cm-1 A 3432 1636 1039 783 693 655 529 470 Hình P3.6. Phổ hồng ngoại của mẫu BAlFe Phụ lục P6 KẾT QUẢ PHÂN TÍCH BET CỦA MỘT SỐ MẪU BENTONIT BIẾN TÍNH SA3100 Serial No. ad48046 Software Version 2.13 Sample ID B40 Start Date 05/24/11 Customer THANG-DHDT Start Time 11:07:53 Operator TIEN Elapsed Time 1 hrs 57 min Sample Wt 0.0973 g Outgas Time 20 min Profile PSD(ADS) Outgas Temperature 150 C Summary Surface Area Report BET Surface area 48.74 sq.m/g Correlation Coefficient 0.98232 Total Pore Volume Report Total Pore Volume 0.1329 ml/g (Ps/Po = 0.9814, Adsorption) Adsorption BJH Pore Size Distribution Pore Dia. Pore Volume % Range(nm) (ml/g) Under 6 0.00320 1.12 6 - 8 0.02214 3.76 8 - 10 0.02357 6.19 10 - 12 0.01283 8.37 12 - 16 0.02234 10.81 16 - 20 0.03431 19.64 20 - 80 0.03469 39.34 Over 80 0.01294 10.77 BJH Total 0.14892 100.00 Page 1 of 13 SA3100 Serial No. ad48046 Software Version 2.13 Sample ID B90 Start Date 10/13/11 Customer THANG-DT Start Time 10:01:42 Operator TIEN Elapsed Time 1 hrs 40 min Sample Wt 0.078 g Outgas Time 20 min Profile PSD(ADS) Outgas Temperature 200 C Summary Surface Area Report BET Surface area 60.724 sq.m/g Correlation Coefficient 0.99953 Total Pore Volume Report Total Pore Volume 0.1644 ml/g (Ps/Po = 0.9814, Adsorption) Adsorption BJH Pore Size Distribution Pore Dia. Pore Volume % Range(nm) (ml/g) Under 6 0.00000 0.00 6 - 8 0.00000 0.00 8 - 10 0.00414 1.06 10 - 12 0.01425 3.66 12 - 16 0.01421 3.65 16 - 20 0.02265 5.81 20 - 80 0.29557 75.87 Over 80 0.03877 9.95 BJH Total 0.38958 100.00 Page 1 of 11 SA3100 Serial No. ad48046 Software Version 2.13 Sample ID B40-LA Start Date 10/12/11 Customer THANG-DT Start Time 11:05:20 Operator TIEN Elapsed Time 1 hrs 40 min Sample Wt 0.1239 g Outgas Time 20 min Profile PSD(ADS) Outgas Temperature 200 C Summary Surface Area Report BET Surface area 79.333 sq.m/g Correlation Coefficient 0.99999 Total Pore Volume Report Total Pore Volume 0.2295 ml/g (Ps/Po = 0.9814, Adsorption) Adsorption BJH Pore Size Distribution Pore Dia. Pore Volume % Range(nm) (ml/g) Under 6 0.01268 5.71 6 - 8 0.00573 2.58 8 - 10 0.00559 2.52 10 - 12 0.00967 4.35 12 - 16 0.01192 5.36 16 - 20 0.01926 8.67 20 - 80 0.12147 54.68 Over 80 0.03582 16.12 BJH Total 0.22214 100.00 Page 1 of 13 SA3100 Serial No. ad48046 Software Version 2.13 Sample ID ALLA-2.0 Start Date 10/12/11 Customer THANG-DT Start Time 13:08:19 Operator TIEN Elapsed Time 1 hrs 24 min Sample Wt 0.1008 g Outgas Time 20 min Profile PSD(ADS) Outgas Temperature 200 C Summary Surface Area Report BET Surface area 181.509 sq.m/g Correlation Coefficient 0.99684 Total Pore Volume Report Total Pore Volume 0.2845 ml/g (Ps/Po = 0.9814, Adsorption) Adsorption BJH Pore Size Distribution Pore Dia. Pore Volume % Range(nm) (ml/g) Under 6 0.00000 0.00 6 - 8 0.00212 0.68 8 - 10 0.00901 2.88 10 - 12 0.02315 7.39 12 - 16 0.02337 7.47 16 - 20 0.03094 9.88 20 - 80 0.18483 59.04 Over 80 0.03963 12.66 BJH Total 0.31305 100.00 Page 1 of 13 SA3100 Serial No. ad48046 Software Version 2.13 Sample ID BALFE-20 Start Date 10/12/11 Customer THANG-DT Start Time 08:28:22 Operator TIEN Elapsed Time 2 hrs 14 min Sample Wt 0.114 g Outgas Time 20 min Profile PSD(ADS) Outgas Temperature 200 C Summary Surface Area Report BET Surface area 131.478 sq.m/g Correlation Coefficient 0.95498 Total Pore Volume Report Total Pore Volume 0.2821 ml/g (Ps/Po = 0.9814, Adsorption) Adsorption BJH Pore Size Distribution Pore Dia. Pore Volume % Range(nm) (ml/g) Under 6 0.00000 0.00 6 - 8 0.00209 0.66 8 - 10 0.00695 2.19 10 - 12 0.01052 3.31 12 - 16 0.02481 7.81 16 - 20 0.02881 9.07 20 - 80 0.19187 60.42 Over 80 0.05252 16.54 BJH Total 0.31758 100.00 Page 1 of 13